个人简历
薛东,1997年本科毕业于陕西美高梅注册化学系。2005年在中国科学院成都有机化学研究所获理学博士学位。2007年10月-2009年12月分别在美国 Colorado State University和 The Scripps Research Institute 从事博士后研究。主要从事光催化剂的设计、合成及其参与的催化反应研究,具有生理活性化合物及手性药物的合成研究。在国际核心期刊Angewandte Chemie International Edition, ACS Catalysis, Organic Letters, Chemistry-A European Journal, Chemical Communications, Green Chemistry等发表研究论文80多篇。获中国发明专利20多项。获得2019年度Thieme Chemistry Journals Award奖项。先后主持国家自然科学基金青年、面上,陕西省自然科学基金,陕西省“创新团队”等科研项目。目前担任陕西美高梅注册美高梅注册教授、博士生导师、院长、应用表面与胶体化学教育部重点实验室主任。中国化学会有机化学专业会委员、绿色化学委员会委员、应用化学委员会委员,国家外专局应用表面与胶体化学引智基地学术委员会委员。
代表性成果
(19) Fei Li, Weikang Xiong, Geyang Song, Yonggang Yan, Gang Li, Chao Wang, Jianliang Xiao, Dong Xue.* Light Promoted Ni-Catalyzed Cross-Coupling of Aryl Chlorides with Hydrazides: Application to the Synthesis of Rizatriptan. Org. Lett.. 2023, 25, 3287–3292.
(18) Geyang Song, Qi Li, Ding-Zhan Nong, Jiameng Song, Gang Li, Chao Wang, Jianliang Xiao, Dong Xue.* Ni-Catalyzed Photochemical C-N Coupling of Amides with (Hetero)aryl Chlorides. Chem. Eur. J. 2023, e202300458.
(17) Yonggang Yan, Gang Li, Jiani Ma, Chao Wang, Jianliang Xiao, and Dong Xue.* Photoinduced Generation of Ketyl Radicals and Application in C−C Coupling without External Photocatalyst. Green Chem., 2023, 10.1039/D3GC00054K.
(16) Liu Yang,# Yonggang Yan,# Ni Cao, Jing Hao, Gang Li, Wei Zhang, Rui Cao, Chao Wang, Jianliang Xiao, and Dong Xue.* Ni(I)-Catalyzed Hydroxylation of Aryl Halides with Water under Thermal Catalysis. Org. Lett. 2022, 24, 9431–9435.
(15) Geyang Song,# Ding-Zhan Nong,# Qi Li, Yonggang Yan, Gang Li, Juan Fan, Wei Zhang, Rui Cao, Chao Wang, Jianliang Xiao,* Dong Xue.* Photochemical Synthesis of Anilines via Ni-Catalyzed Coupling of Aryl Halides with Ammonium Salts. ACS Catal. 2022, 12, 15590–15599.
(14) Geyang Song,# Ding-Zhan Nong,# Jing-Sheng Li, Gang Li, Wei Zhang, Rui Cao, Chao Wang, Jianliang Xiao,* Dong Xue.* General Method for the Amination of Aryl Halides with Primary and Secondary Alkyl Amines via Nickel Photocatalysis. J. Org. Chem. 2022, 87, 10285-10297. (Highlight by Organic Chemistry Portal, http://www.organic-chemistry.org/abstracts/lit8/598.shtm).
(13) Geyang Song, Dong Xue.* Research Progress on Light-Promoted Transition Metal-Catalyzed C-Heteroatom Bond Coupling Reactions. Chin. J. Org. Chem. 2022, 42, 2275-2299 (约稿, 封面).
(12) Yonggang Yan, Jinjin Sun, Gang Li, Liu Yang, Wei Zhang, Rui Cao, Chao Wang, Jianliang Xiao, Dong Xue*. Photochemically Enabled, Ni-Catalyzed Cyanation of Aryl Halides. Org. Lett. 2022, 24, 2271-2275. (Highlight by Synfacts. 2022, 18, 0630; Organic Chemistry Portal, http://www.organic-chemistry.org/abstracts/lit8/379.shtm).
(11)Liu Yang, Dong Xue.* Transition-Metal-Catalyzed Hydroxylation Reaction of Aryl Halide for the Synthesis of Phenols. Synlett 2021, 32, 1891–1896 (约稿).
(10) Geyang Song, Liu Yang, Jing-Sheng Li, Wei-Jun Tang, Wei Zhang, Rui Cao, Chao Wang, Jianliang Xiao,* Dong Xue.* Chiral Arylated Amines via C-N Coupling of Chiral Amines with Aryl Bromides Promoted by Light. Angew. Chem. Int. Ed, 2021, 60, 21536-21542.
(9) Gang Li, Liu Yang, Jian-Jun Liu, Wei Zhang, Rui Cao, Chao Wang, Zunting Zhang, Jianliang Xiao, and Dong Xue.* Light-Promoted C–N Coupling of Aryl Halides with Nitroarenes. Angew. Chem. Int. Ed, 2021, 60, 5230-5234.
(8) Liu Yang, Huan-Huan Lu, Chu-Hui Lai, Gang Li, Wei Zhang, Rui Cao, Fengyi Liu, Chao Wang, Jianliang Xiao, Dong Xue.* Light-Promoted Nickel Catalysis: Etherification Aryl Electrophiles with Alcohols Catalyzed by a NiII-Aryl Complex. Angew. Chem. Int. Ed, 2020, 59, 12714-12719.
(7) Liu Yang, Zhiyan Huang, Gang Li, Wei Zhang, Rui Cao, Chao Wang, Jianliang Xiao, Dong Xue.* Synthesis of Phenols: Organophotoredox/Nickel Dual Catalytic Hydroxylation of Aryl Halides with Water. Angew. Chem. Int. Ed, 2018, 57, 1968-1972.
(6) Xiaojun Guo, Xialiang Li, Xiao-Chen Liu, Ping Li, Zhen Yao, Jianfeng Li, Wei Zhang, Jian-Ping Zhang, Dong Xue,* Rui Cao.* Selective Visible-light-driven Oxygen Reduction to Hydrogen Peroxide Using BODIPY Photosensitizers. Chem. Commun, 2018, 54, 845-848.
(5) Xiaojun Guo, Wei Ma, Dong Xue,* Chao Wang, Jianliang Xiao.* Palladium-Catalyzed Ylidyl-Carbonylation of Aryl Halides To Produce α‑Acylphosphoranes. Org. Lett, 2016, 18, 4824-4827.
(4) Mengzhou Wang, Yanyan Zhang, Tao Wang, Chao Wang, Dong Xue,* Jianliang Xiao. Story of an Age-Old Reagent: An Electrophilic Chlorination of Arenes and Heterocycles by 1‑Chloro-1,2-benziodoxol-3-one. Org. Lett, 2016, 18, 1976-1979.
(3) Xiao-Fei Wang, Shu-Sheng Yu, Chao Wang, Jianliang Xiao, Dong Xue.* BODIPY Catalyzed Amide Synthesis Promoted by BHT and Air under Visible Light, Org. Biomol. Chem, 2016, 14, 7028-7037.
(2) Wei Ma, Dong Xue,* Ting Yu, Chao Wang, Jiangliang Xiao.* Carbonylative coupling of allylic acetates with aryl boronic acids. Chem. Commun, 2015, 42, 8797-8800.
(1) Dong Xue,* Zhi-Hui Jia, Cong-Jun Zhao, Yan-Yan Zhang, Chao Wang, Jianliang Xiao. Direct Arylation of N-Heteroarenes with Aryldiazonium Salts by Photoredox Catalysis in Water. Chem. - Eur. J, 2014, 10, 2960-2965.