个人简介
一、教育工作经历
2015/01-至今, 陕西美高梅注册,美高梅注册,博士生导师,教授;
2014/05-2016/05,美国加州大学河滨分校,博士后;
2011/04-2012/04,美国加州大学河滨分校,访问学者;
2010/01-2014/12,陕西美高梅注册,美高梅注册,硕士生导师,副教授;
2007/07-2009/12,陕西美高梅注册,化学与材料科学学院,讲师;
2004/09-2007/05,中国科学院,福建物质结构研究所,博士;
1997/09-2004/07,陕西美高梅注册,化学教育,学士; 分析化学,硕士。
二、主要研究兴趣
◙ 吸附与分离
基于配位合成化学和晶体工程原理,精准设计合成和功能化修饰新型功能配合物、配位聚合物、金属-有机框架(MOFs)、共价有机框架(COFs)、氢键有机框架(HOFs)等晶态多孔材料,研究其在温室气体捕获、低碳烃分离、清洁能源气体存储、可挥发性污染物去除、盐湖卤水中锂、铷、铯资源提取等能源环境领域的应用。
◙ 传感与催化
基于配位晶态材料及其衍生的多孔碳、多孔氧化物及其复合物材料的多孔性和导电性能,研究其作为新型光电传感材料,质子传导材料和高效化学催化、光催化和电催化材料的开发与利用。
◙ 储能与电池
基于新型多孔配位晶态材料及其衍生的多孔碳、多孔氧化物及其复合物材料,研究其在超级电容器、锂离子电池、锂-硫电池、燃料电池等绿色储能和电池技术等方面的应用。
三、代表性成果简介
立足[M3O]氧心三核簇配位合成化学,系统发展了金属-有机框架材料(MOFs)精准结构设计与性能调控新策略;发展了多孔配位框架材料的孔道分区策略,开发了具备空前结构组成和性能可调控性的多孔材料平台;提出了多组分金属协同结晶策略,促进了含高价金属多孔材料的结晶,极大调控了MOFs材料的气体捕集分离性能;利用金属有机多面体外表面作为质子载体,发展了新型高性能质子导电材料研究的新思路,获得了具备极高质子导电性能的新材料;基于离子液体绿色溶剂,开创了溶剂诱导合成新型非中心对称晶态材料的新方法,开辟了多元卤氰合亚铜和混金属铅卤化物晶态材料制备的新途径;系统调控了多氮唑的配位化学,将多金属氧酸盐和三氮唑配位化学创造性地结合,发展了多酸基无机-有机主客体化学等。
入选教育部“高层次人才奖励计划”青年学者、教育部“新世纪优秀人才”支持计划、教育部首批全国高校“双带头人”教师党支部书记工作室负责人、陕西省首批“杰出青年科学基金”、陕西高校青年创新团队负责人、陕西省“青年科技新星”、陕西美高梅注册美高梅注册“腾飞计划学者”等。主持国家重点研发计划子课题1项,国家自然科学基金项目4项,陕西省自然科学基金青年项目1项,陕煤联合基金项目1项,中央高校基金创新团队项目2项等。以第一或通讯作者在包括J. Am. Chem. Soc.,Angew. Chem. Int. Ed.,Nat. Commun.,Adv. Mater.,Acc. Chem. Res.,Chem. Mater.,Chem. Commun.,Chem. Eur. J.,Inorg. Chem. 等国际顶级期刊发表研究论文100余篇,论文累计被引用7000余次,h-指数为40。获授权中国发明专利10余项。获陕西省自然科学奖二等奖1项,三等奖1项,陕西高等学校科学技术奖一等奖2项等。
四、承担科研项目
◙ 国家重点研发计划“纳米前沿”重点专项,“超高灵敏检测痕量危险有害化学物质的纳米材料与技术”项目 (课题一:光敏晶态有机纳米孔材料研制),2023-2028,课题负责人;
◙ 国家自然科学基金面上项目,22071140,基于精准孔道分区突破Trade-off效应实现金属-有机框架高效气体吸附分离性能研究,2021/01-2024/12,主持;
◙ 陕煤联合基金项目,2021JLM-20,基于MOF多孔材料实现热解煤气高效吸附分离与催化转化研究,2021/01-2023/12,主持;
◙ 中央高校基金-创新团队项目,GK202101002,“功能配位合成化学”创新团队,2021/01-2023/12,主持;
◙ 陕西省杰出青年科学基金,2018JC-019, 功能配位晶态材料的可控制备与性能调控,2018/01-2020/12, 主持;
◙ 国家自然科学基金面上项目,21671126,镁基多孔配位框架材料的设计合成及其在CO2捕集和转化中的应用,2017/01-2020/12, 主持;
◙ "腾飞计划学者",陕西美高梅注册美高梅注册,2017/07-2020/07,主持;
◙ 中央高校基金-创新团队项目,GK201701003,2017/01-2019/12,主持;
◙ 教育部新世纪优秀才支持计划,NCET-12-0897,2013/01-2015/12,主持;
◙ 陕西省青年科技新星,2014KJXX-50,2014/01-2016/12,主持;
◙ 国家自然科学基金面上项目,21271123,基于咪唑类离子液体构筑非中心对称功能化合物及其光电性能研究,2013/01-2016/12,主持;
◙ 国家自然科学基金青年项目,20801033,离子热合成气体吸附和阳离子交换双功能多孔配位聚合物研究,2009/01-2011/12,主持;
◙ 陕西省自然科学基金青年项目,2010JQ2010,多孔配位聚合物晶态材料的离子热合成、结构及气体吸附和离子交换性能研究,2010/01-2011/12,主持;
◙ 福建省纳米材料重点实验室开放基金,NM10-08,配位聚合物型纳米材料的离子热合成,2010/01-2012/12,主持;
◙ 国家自然科学基金面上项目,20871035,重稀碱金属(铷、铯)盐-混合溶剂体系相化学及热力学性质研究,2009/01-2011/12,第二人;
◙ 国家自然科学基金面上项目,20876094,基于定位突变分子设计的氯过氧化物酶手性催化活性研究,2009/01-2011/12,第三人。
研究成果目录
一、发表论文
2023
◙ Jia-Wen Wang, Shu-Cong Fan, Hai-Peng Li, Xianhui Bu*, Ying-Ying Xue, Quan-Guo Zhai*, De-linker-enabled exceptional volumetric acetylene storage capacity and benchmark C2H2/C2H4 and C2H2/CO2 separations in metal-organic frameworks, Angewandte Chemie International Edition, 2023, e202217839.
◙ Peng Zhang*, Qian-Cheng Luo, Zhenhua Zhu, Wanrong He, Nan Song, Junting Lv, Xuning Wang, Quan-Guo Zhai*, Yan-Zhen Zheng*, Jinkui Tang*, Radical-bridged heterometallic single-molecule magnets incorporating four lanthanoceniums, Angewandte Chemie International Edition, 2023, e202218540.
◙ Hai-Peng Li, Jia-Wen Wang, Quan-Guo Zhai*, Development of MOF-5-like ultra-microporous metal-squarate frameworks for efficient acetylene storage and separation, Journal of Materials Chemistry A, 2023.
◙ Jia-Min Huo, Ze-Lin Ma, Ying Wang*, Yi-Jia Cao, Yu-Cheng Jiang, Shu-Ni Li*, Yu Chen, Man-Cheng Hu, Quan-Guo Zhai*, Monodispersed Pt sites supported on NiFe-LDH from synchronous anchoring and reduction for high efficiency overall water splitting, Small, 2023, 2207044.
◙ Hong-Juan Lv, Qadeer Ul Hassan, Shu-Cong Fan, Ying Wang, Yurong An, Gang-Qiang Zhu, Yu-Cheng Jiang, Wen-Yu Yuan*, Quan-Guo Zhai*, Ultrafine Pd nanoparticles anchored on hierarchically porous titanium-based MOFs for superior photothermal CO2 reduction, Science China Materials, 2023, 66, 2317–2328.
◙ Li-Qiu Yang, Jia Yu, Peng Zhang, Ying Wang, Wen-Yu Yuan, Quan-Guo Zhai*, Controllable C2H2/CO2 inverse adsorption and separation in pillar-layered Zn-1,2,4-triazolate-dicarboxylate frameworks induced by the ligand aromaticity, Separation and Purification Technology, 2023.
◙ Jia-Min Huo, Ying Wang*, Jiang-Nan Xue, Wen-Yu Yuan, Quan-Guo Zhai*, Man-Cheng Hu, Shu-Ni Li*, Yu Chen, High-valence metal doping induced lattice expansion for M-FeNi LDH toward enhanced urea oxidation electrocatalytic activities, Small, 2023.
◙ Jiao Lei, Wenyu Yuan, Jianxuan Shang*, Jie Xu, Peng Zhang, Ying Wang, Yong-Peng Li, Quan-Guo Zhai*, Development of mixed multinuclear cluster strategy in metal-organic frameworks for methane purification and storage, Inorganic Chemistry, 2023.
◙ Shu-Yi Li, Kun Wang, Jia-Wen Wang, Shu-Cong Fan, Peng Zhang, Quan-Guo Zhai*, Pore environmental modification by alkoxy groups in pore-space-partitioned metal−organic frameworks to achieve gas uptake-selectivity balance, Inorganic Chemistry, 2023, 62, 7069−7078.
◙ Hong-Juan Lv, Shu-Cong Fan, Yu-Cheng Jiang*, Shu-Ni Li, Quan-Guo Zhai*, Design of robust rod-packing scandium-organic framework for C2Hx/CO2 separation, CO2 storage and catalytic CO2 cycloaddition, Inorganic Chemistry Frontiers, 2023, 10, 3015–3024.
◙ Shuo Wang, Ying Wang, Jia-Min Huo, Wen-Yu Yuan*, Peng Zhang, Shu-Ni Li, and Quan-Guo Zhai*, Multivariate indium-organic frameworks for highly efficient carbon dioxide capture and electrocatalytic conversion, Inorganic Chemistry Frontiers, 2023, 10, 158–167.
◙ Xiao-Bing Mu, Ying-Ying Xue, Man-Cheng Hu*, Peng Zhang, Ying Wang, Hai-Peng Li, Shu-Ni Li, Quan-Guo Zhai*, Fine-tuning of pore-space-partitioned metal-organic frameworks for efficient C2H2/C2H4 and C2H2/CO2 separation, Chinese Chemical Letters, 2023, 34, 107296.
◙ Wanrong He, Xiao-Bing Mu, Jiao Lei, Wenyu Yuan*, Peng Zhang, Quan-Guo Zhai*, Novel pillared-layer-like metal-organic frameworks with quadrilateral channels for efficient separation of C2H2 from C2H2/CO2 and C2H2/C2H4 mixtures, Crystal Growth & Design, 2023, 23, 4346−4356.
◙ Jie Meng, Jing Zhang, Shu-Cong Fan, Ying Wang, Peng Zhang*, Wen-Yu Yuan, Quan-Guo Zhai*, Cage-space-partitioned metal-organic frameworks for efficient carbon dioxide capture and conversion, Crystal Growth & Design, 2023, 23, 5043−5051.
◙ Cun Gao, Xiao-Bing Mu, Wen-Yu Yuan*, Peng Zhang, Ying Wang, Quan-Guo Zhai*, Construction of new multi-cage-based MOFs using flexible triangular ligands for efficient gas adsorption and separation, Journal of Solid State Chemistry, 2023, 123994.
◙ Yong-Peng Li*, Jing-Jing Ni, Shu-Cong Fan, Quan-Guo Zhai*, Auxiliary ligand-directed assembly of a non-interpenetrated cage-within-cage metal-organic framework for highly efficient C2H2/CO2 separation, Chinese Journal of Structural Chemistry, 2023, 100070.
◙ Synthesis, Properties and Applications of Crystalline Porous Materials, Edited by Quan-Guo Zhai, Jiandong Pang, Chinese Journal of Structural Chemistry, February 2023, Volume 42, Issue 2.
◙ Xuefang Zhu, Xing Fan, Haiping Lin, Shuni Li, Quan-Guo Zhai, Yucheng Jiang*, Yu Chen*, Highly efficient electroenzymatic cascade reduction reaction for the conversion of nitrite to ammonia, Advaned Energy Materials, 2023, 2300669.
2022
◙ Ying Wang, Shuo Wang, Ze-Lin Ma, Li-Ting Yan, Xue-Bo Zhao, Ying-Ying Xue, Jia-Min Huo, Xiao Yuan, Shu-Ni Li, Quan-Guo Zhai*, Competitive coordination-oriented monodispersed ruthenium sites in conductive MOF/LDH heteronanotree catalysts for efficient overall water splitting in alkaline media, Advanced Materials, 2022, 2107488.
◙ Jia Yu, Jing Zhang, Peng Zhang*, Ying Wang, Shu-Ni Li, Quan-Guo Zhai*, Controllable inverse C2H2/CO2 separation in ultra-stable Zn-organic frameworks for efficient removal of trace CO2 from acetylene, Journal of Materials Chemistry A, 2022, 10, 23630–23638.
◙ Shu-Yi Li, Xin Yan, Jiao Lei, Wen-Juan Ji*, Shu-Cong Fan, Peng Zhang, Quan-Guo Zhai*, High-performance turn-on fluorescent metal−organic framework for detecting trace water in organic solvents based on the excitedState intramolecular proton transfer mechanism, ACS Applied Materials & Interfaces, 2022, 14, 55997−56006.
◙ Hai-Peng Li, Zhao-Di Dou, Yi Xiao, Guan-Jiang Fan, Dong-Chen Pan, Man-Cheng Hu, Quan-Guo Zhai*, Rational regulation of acetylene adsorption and separation for ultra-microporous copper-1,2,4-triazolate frameworks by halogen hydrogen bonds, Nanoscale, 2022, 14, 18200–18208.
◙ Xuefang Zhu, Yu Ding, Shuni Li, Yu Chen, Quan-Guo Zhai*, Yucheng Jiang*, Efficient electroenzymatic cascade catalysis for ortho-selective chlorination of phenol, ACS Sustainable Chemistry & Engineering, 2022, 10, 12497−12503.
◙ Shu-Cong Fan, Shuang-Qiu Chen, Jia-Wen Wang, Yong-Peng Li*, Peng Zhang, Ying Wang, Wenyu Yuan, Quan-Guo Zhai*, Precise introduction of single vanadium site into indium-organic framework for CO2 capture and photocatalytic fixation, Inorganic Chemistry, 2022, 61, 14131−14139.
◙ Yong-Peng Li, Shu-Cong Fan, Guo-Tong Zhang, Quan-Guo Zhai*, Pore window partitions in metal-organic frameworks for highly efficient reversed ethylene/ethane separations, Inorganic Chemistry, 2022, 61, 10493–10501.
◙ Hong-Juan Lv, Jian-Wei Zhang, Yu-Cheng Jiang*, Shu-Ni Li, Man-Cheng Hu, Quan-Guo Zhai*, Micropore regulations in ultra-stable [Sc3O]-organic frameworks for acetylene storage and purification, Inorganic Chemistry, 2022, 61, 3553–3562.
◙ Xin Yan, Jiao Lei, Yong-Peng Li, Peng Zhang*, Ying Wang, Shu-Ni Li, Quan-Guo Zhai*, Modulating fluorescence sensing properties of excited-state intramolecular proton transfer (ESIPT) based metal organic frameworks (MOF) by metal polarization, CrystEngComm, 2022, 24, 2264–2269.
◙ Jiao Lei, Peng Zhang,* Ying-Ying Xue, Jie Xu,* Hai-Peng Li, Hong-Juan Lv, Ying Wang, Shu-Ni Li, Quan-Guo Zhai*, Design of Ultra-Stable Yttrium-Organic Framework Adsorbents for Efficient Methane Purification and Storage, Separation and Purification Technology, 2022, 283, 120211.
◙ Qadeer Ul Hassan, Ali Imran Channa, Quan-Guo Zhai*, Gangqiang Zhu*, Yongxiang Gao, Nisar Ali, Muhammad Bilal, Recent advancement in Bi5O7I-based nanocomposites for high performance photocatalysts, Chemosphere, 2022, 288, 132668.
◙ Jing Zhang, Ying-Ying Xue, Peng Zhang*, Hai-Peng Li, Ying Wang, Jie Xu*, Shu-Ni Li, Quan-Guo Zhai*, Honeycomb-like pillar-layered metal-organic frameworks with dual porosity for efficient C2H2/CO2 and C2H2/C2H4 separations, Crystal Growth & Design, 2022, 22, 469−477.
◙ Jia-Min Huo, Ying Wang*, Jie Meng, Xin-Yi Zhao, Quan-Guo Zhai, Yu-Cheng Jiang, Man-Cheng Hu, Shu-Ni Li*, Yu Chen, π···π interaction directed 2D FeNi-LDH nanosheets from 2D Hofmann-MOFs for the oxygen evolution reaction, Journal of Materials Chemistry A, 2022, 10, 1815-1820.
2021
◙ Ying-Ying Xue, Xiao-Ying Bai, Jing Zhang, Ying Wang, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu, Quan-Guo Zhai*, Precise pore space partition combined with high-density hydrogen-bonding acceptor within a metal-organic framework for highly efficient acetylene storage and separation, Angewandte Chemie International Edition, 2021, 60, 10122-10128.
◙ Ying Wang, Liting Yan, Kamran Dastafkan, Chuan Zhao*, Xuebo Zhao, Yingying Xue, Jiamin Huo, Shuni Li, Quan-Guo Zhai*, Lattice matching growth of conductive hierarchical porous MOF/LDH heteronanotube arrays for highly efficient water oxidation, Advanced Materials, 2021, 2006351.
◙ Yong-Peng Li, Yong-Ni Zhao, Shu-Ni Li, Da-Qiang Yuan, Yu-Cheng Jiang, Xianhui Bu*, Man-Cheng Hu, Quan-Guo Zhai*, Ultra-high uptake capacity-enabled gas separation and fruit preservation by a new single-walled nickel-organic framework, Advanced Science, 2021, 2003141.
◙ Jiao Lei, Bingqiang Wang, Yong-Peng Li, Wen-Juan Ji, Ke Wang, Honglan Qi, Pi-Tai Chou*, Miao-Miao Zhang, Hongtao Bian, Quan-Guo Zhai*, A new molecular recognition concept: multiple hydrogen bonds and their optically triggered proton transfer in confined metal-organic frameworks for superior sensing element, ACS Applied Materials & Interfaces, 2021, 13, 22457-22465.
◙ Shu-Cong Fan, Yun-Tong Li, Ying Wang*, Jia-Wen Wang, Ying-Ying Xue, Hai-Peng Li, Shu-Ni Li, Quan-Guo Zhai*, Amide-functionalized metal-organic frameworks coupled with open Fe/Sc sites for efficient acetylene purification, Inorganic Chemistry, 2021, 60, 18473-18482.
◙ Jian-Wei Zhang, Hui Li, Jie-Qiong Li, Ya Chen, Peng Qu*, Quan-Guo Zhai*, Enhancement of the fluorescence properties via introducing the tetraphenylethylene chromophores into a novel Mn–organic framework with a rare [Mn4(μ3-OH)2] cluster, Dalton Transactions, 2021, 50, 17482-17486.
◙ Guodong Han, Teng Deng, Xuechao Jiao, Xinliang Men, Juan Wang*, Ying Wang*, Quan-Guo Zhai*, Indium-based MOFs and carbon nanotube embedded efficient cathodes for high‑performance lithium‑sulfur batteries, Ionics, 2021, 27, 5115–5125.
◙ Hai-Peng Li, Ying-Ying Xue, Ying Wang, Huaming Sun, Man-Cheng Hu*, Shu-Ni Li, Yucheng Jiang, Quan-Guo Zhai*, Regulation on topological architectures and gas adsorption for cadmium-azolate-carboxylate frameworks by the ligand flexibility, Crystal Growth & Design, 2021. 21, 1718-1726.
◙ Xin Yan, Yong-Peng Li, Jiao Lei, Ying Wang, Shu-Ni Li, Quan-Guo Zhai*, Introduction of continuous excited-state intermolecular proton transfer process into open yttrium-terephthalate framework for ratiometric fluorescent fluorion detection, Journal of Solid State Chemistry, 2021, 300, 122212.
◙ Qing-Ling Hong, Quan-Guo Zhai, Xiao-Li Liang, Yun Yang, Fu-Min Li, Yu-Cheng Jiang, Man-Cheng Hu, Shu-Ni Li, Yu Chen, Holey cobalt oxyhydroxide nanosheets for the oxygen evolution reaction, Journal of Materials Chemistry A, 2021, 9, 3297–3302.
2020
◙ Hai-Peng Li, Zhao-Di Dou, Ying Wang; Ying-Ying Xue, Yong-Peng Li, Man-Cheng Hu*, Shu-Ni Li, Yucheng Jiang, Quan-Guo Zhai*, Tuning the pore surface of an ultra-microporous framework for enhanced methane and acetylene purification performance, Inorganic Chemistry, 2020, 59, 16725-16736.
◙ Hui Gao, Yan-Bin He, Juan-Juan Hou, Quan-Guo Zhai*, Xian-Ming Zhang*, Enhanced proton conductivity by aliovalent substitution of cadmium for indiumin dimethylaminium templated metal anilicates, ACS Applied Materials & Interfaces, 2020, 12, 41605-41612.
◙ Jian-Wei Zhang, Peng Qu*, Man-Cheng Hu, Shu-Ni Li, Yu-Cheng Jiang, Quan-Guo Zhai*, Self-assembly of a rare nanocage-based Fe-MOF toward high methane purification performance, Crystal Growth & Design, 2020, 20, 5657-5663.
◙ Yun-Tong Li, Jian-Wei Zhang*, Hong-Juan Lv, Man-Cheng Hu, Shu-Ni Li, Yu-Cheng Jiang, Quan-Guo Zhai*, Tailoring the pore environment of a robust Ga-MOF by deformed [Ga3O(COO)6] cluster for boosting C2H2 uptake and separation, Inorganic Chemistry, 2020, 59, 10368−10373.
◙ Jiamin Huo, Ying Wang*, Liting Yan, Yingying Xue, Shuni Li, Mancheng Hu*, Yucheng Jiang, Quan-Guo Zhai*, In situ semi-transformation from heterometallic MOFs to Fe-Ni LDH/MOF hierarchical architectures for boosted oxygen evolution reaction, Nanoscale, 2020, 12, 14514–14523.
◙ Wen-Juan Ji, Gui-Fang Liu, Bing-Qiang Wang, Wen-Bo Lu, Quan-Guo Zhai*, Design of a heterometallic Zn/Ca-MOF decorated by alkoxy on the pore surface exhibiting high fluorescence sensing performance for Fe3+ and Cr2O72−, CrystEngComm, 2020, 22, 4710–4715.
◙ Ying Wang, Ying-Ying Xue, Liting Yan, Hai-Peng Li, Yong-Peng Li, En-Hui Yuan, Meng Li, Shuni Li, Quan-Guo Zhai*, Multi-metal incorporation into 2D conductive metal-organic frameworks nanowires enables top-level electrocatalytic oxidation of benzylamine to benzonitrile, ACS Applied Materials & Interfaces, 2020, 12, 24786−24795.
◙ Hong-Juan Lv, Yong-Peng Li, Ying-Ying Xue, Yu-Cheng Jiang*, Shu-Ni Li, Man-Cheng Hu, Quan-Guo Zhai*, Systematic regulation on the C2H2/CO2 separation by 3p-block open metal sites in a robust metal-organic framework platform, Inorganic Chemistry, 2020, 59, 4825-4834.
◙ Ying-Ying Xue, Jian-Wei Zhang, Yong-Peng Li, Hai-Peng Li, Ying Wang*, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu, Quan-Guo Zhai*, The mimic of ferroalloy to develop a bifunctional Fe-organic framework platform for enhanced gas sorption and efficient oxygen evolution electrocatalysis, ACS Applied Materials & Interfaces, 2020, 12, 4432-4442.
◙ Hai-Tao Wu, Hai-Peng Li, Shu-Ni Li*, Yu-Cheng Jiang, Man-Cheng Hu, Quan-Guo Zhai*, Design of a pillar-layered metal-organic framework as high-performance fluorescence sensor for nitroaromatic compounds, Journal of Solid State Chemistry, 2020, 283, 121166.
◙ Lishi Lu, Hai-Zhu Zhang, Ying Wang*, Yingying Xue, Haipeng Li, Shuni Li, Mancheng Hu, Yucheng Jiang, Quan-Guo Zhai*, The evolution of bimetal hydroxide fragments from brucite to goethite in metal-organic frameworks for enhanced oxygen evolution reaction, Journal of Solid State Chemistry, 2020, 292, 121751.
2019
◙ Yong-Peng Li, Ying Wang, Ying-Ying Xue, Hai-Peng Li, Quan-Guo Zhai*, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu, Xianhui Bu*, Ultramicroporous building unit as a path to bi-microporous metal-organic framework with high acetylene storage and separation performance, Angewandte Chemie International Edition, 2019, 58, 13590-13595.
◙ Ying-Ying Xue, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu, Quan-Guo Zhai*, Quest for 9-connected robust metal-organic framework platforms on the base of [M3(O/OH)(COO)6(pyridine)3] cluster as excellent gas separation and asymmetric supercapacitor materials, Journal of Materials Chemistry A, 2019, 7, 4640-4650.
◙ Jian-Wei Zhang, Peng Qu,* Man-Cheng Hu, Shu-Ni Li, Yu-Cheng Jiang, Quan-Guo Zhai*, Topology-guided design for Sc-soc-MOFs and their enhanced storage and separation for CO2 and C2-hydrocarbons, Inorganic Chemistry, 2019,58, 16792−16799.
◙ Hai-Peng Li, Zhaodi Dou, Shuang-Qiu Chen, Mancheng Hu*, Shuni Li, Hua-Ming Sun*, Yucheng Jiang, Quan-Guo Zhai*, Design of a multifunctional indium-organic framework: fluorescent sensing of nitro compounds, physical adsorption and photocatalytic degradation of organic dyes, Inorganic Chemistry, 2019, 58, 11220-11230.
◙ Zhen-Qiang Du,‡ Yong-Peng Li,‡ Xing-Xia Wang, Juan Wang*, Quan-Guo Zhai*, Enhanced electrochemical performance of Li–Co-BTC ternary metal–organic frameworks as cathode materials for lithium-ion batteries, Dalton Transactions, 2019, 48, 2013-2018. (‡co-first author)
◙ Yong-Peng Li, Xiao-Han Zhu, Shu-Ni Li*, Yu-Cheng Jiang, Man-Cheng Hu, Quan-Guo Zhai*, Highly selective and sensitive turn-off-on fluorescent probes for sensing Al3+ ions designed by regulating the ESIPT process in metal-organic frameworks, ACS Applied Material and Interfaces, 2019, 11, 11338-11348.
◙ Jian-Wei Zhang, Wen-Juan Ji, Man-Cheng Hu, Shu-Ni Li, Yu-Cheng Jiang, Xian-Ming Zhang*, Peng Qu, Quan-Guo Zhai*, Superstable 3p-block metal-organic framework platform towards prominent CO2 and C1/C2-hydrocarbon uptake and separation performance and strong Lewis acid catalysis for CO2 fixation, Inorganic Chemistry Frontiers, 2019,6, 813-819.
◙ Yuan Wang, Xitong Chen, Quan-Guo Zhai, Jian Guo, Pingyun Feng, Ultraporous nitrogen-rich carbon nanosheets derived from the synergy of eutectic liquid and zeolitic imidazolate for energy applications, Journal of Power Sources, 2019, 434, 126678.
◙ Wen-Juan Ji, Wei-Wei Pei, Bing-Qiang Wang, Gui-Fang Liu, Bo Yan, Shu-Qin Yao, Quan-Guo Zhai*, Decoration of bare carboxyl group on the pore surface of metal-organic frameworks for high selective fluorescence Fe3+ detection, Journal of Solid State Chemistry, 2019, 274, 18-25.
◙ Hui Gao, Min-Min Liu, Quan-Guo Zhai*, Xing-Xing Wei, Jin-Xiang Yang, Xian-Ming Zhang*, Continuous regulation of the architectures of cupric tetrazolate coordination polymers via the pH and temperature, Journal of Solid State Chemistry, 2019, 276, 244-250.
◙ Xia Gao, Quan-Guo Zhai, Mancheng Hu, Shuni Li, Jie Song, Yucheng Jiang, Design and preparation of stable CPO/HRP@H‐MOF(Zr) composites for efficient bio-catalytic degradation of organic toxicants in wastewater, Journal of Chemical Technology & Biotechnology, 2019, 94, 1249-1258.
◙ Xia Gao, Yu Ding, Yude Sheng, Mancheng Hu, Quan-Guo Zhai, Shuni Li, Yucheng Jiang, Yu Chen, Enzyme immobilization in MOF‐derived porous NiO with hierarchical structure: an efficient and stable enzymatic reactor, CHEMCATCHEM, 2019, 11, 2828-2836.
◙ Jiao Lei, Yong-Peng Li, Ying-Ying Xue, Ying Wang, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu, Quan-Guo Zhai*, Design of robust rod-packing [In(OH)(BDC)] frameworks and their high CO2/C2-hydrocarbons over CH4 separation performance, Journal of Solid State Chemistry, 2019, 279, 120936.
2018
◙ Yong-Peng Li, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu, Quan-Guo Zhai*, A semiconductor and fluorescence dual mode room-temperature ammonia sensor achieved by decorating hydroquinone into metal-organic framework, Chemical Communications, 2018, 54, 9789-9792.
◙ Xiao-Juan Lei, Xiang-Yang Hou*, Shu-Ni Li, Yu-Cheng Jiang, Guo-Xin Sun*, Man-Cheng Hu, Quan-Guo Zhai*, Design of high-symmetrical magnesium-organic frameworks with acetate as modulator and their fluorescence sensing performance, Inorganic Chemistry, 2018, 57, 14280-14289.
◙ Jian-Wei Zhang, Man-Cheng Hu, Shu-Ni Li, Yu-Cheng Jiang, Peng Qu, Quan-Guo Zhai*, Assembly of [Cu2(COO)4] and [M3(μ3-O)(COO)6] (M = Sc, Fe, Ga, and In) building blocks into porous frameworks towards ultra-high C2H2/CO2 and C2H2/CH4 separation performance, Chemical Communications, 2018, 54, 2012-2015.
◙ Xiang-Yang Hou, Xiao-Li Yan, Xiao Wang*, Shu'ni Li, Yucheng Jiang, Mancheng Hu, Quan-Guo Zhai*, Excellent supercapacitor performance of robust nickel-organic framework materials achieved by tunable porosity, inner-cluster redox and in-situ fabrication with graphene oxide, Crystal Growth & Design, 2018, 18, 6035−6045.
◙ Wen-Juan Ji, Rui-Qing Hao, Wei-Wei Pei, Lin Feng, Quan-Guo Zhai*, Design of two isoreticular Cd-biphenyltetracarboxylate frameworks for dye adsorption, separation and photocatalytic degradation, Dalton Transactions , 2018, 47, 700–707.
◙ Hai-Peng Li, Shu-Ni Li, Hua-Ming Sun, Man-Cheng Hu, Yu-Cheng Jiang, Quan-Guo Zhai*, Tuning the CO2 and C1/C2 hydrocarbon capture and separation performance for a Zn-F-triazolate framework through functional amine groups, Crystal Growth & Design, 2018, 18, 3229-3235.
◙ Haipeng Li, Shu'ni Li*, Xiangyang Hou, Yucheng Jiang, Mancheng Hu, Quan-Guo Zhai*, Enhanced gas separation performance of an ultramicroporous pillared-layer framework induced by hanging bare Lewis basic pyridine groups, Dalton Transactions, 2018, 47, 9310–9316.
◙ Xiang-Yang Hou, Xiao-Li Yan, Xiao Wang*, Quan-Guo Zhai*, Tuning the porosity of mesoporous NiO through calcining isostructural Ni-MOFs toward supercapacitor applications, Journal of Solid State Chemistry, 2018, 263, 72–78.
2017
◙ Quan-Guo Zhai, Xianhui Bu, Xiang Zhao, Dong-Sheng Li, Pingyun Feng, Pore space partition in metal-organic frameworks, Accounts of Chemical Research, 2017, 50, 407-417.
◙ Yong-Peng Li, Xing-Xia Wang, Shu-Ni Li, Hua-Ming Sun*, Yu-Cheng Jiang, Man-Cheng Hu, Quan-Guo Zhai*, The power of heterometallation through lithium for helix chain-based noncentrosymmetric MOFs with tunable SHG effects, Crystal Growth & Design, 2017, 17, 5634-5639.
◙ Mengfan Xia, Caixia Zhuo, Xuejuan Ma, Xiaohong Zhang, Huaming Sun, Quan-Guo Zhai*, Yaodong Zhang*, Assembly of the active center of organophosphorus hydrolase in metal–organic frameworks via rational combination of functional ligands, Chemical Communications, 2017, 53, 11302-11305.
◙ Xitong Chen, Xianhui Bu, Qipu Lin, Chengyu Mao, Quan-Guo Zhai, Yuan Wang, Pingyun Feng, Selective ion exchange and photocatalysis by zeolite-like semiconducting chalcogenide, Chemistry - A European Journal, 2017, 49, 11913–11919.
◙ Xiang-Yang Hou, Xiao Wang, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu, Quan-Guo Zhai*, Gas uptake and supercapacitor performance of a highly connected porous Co-metal−organic framework induced by ligand bulk, Crystal Growth & Design, 2017, 17, 3229-3235.
◙ Ya-Li Zhang, Rui Ding, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu, Quan-Guo Zhai*, Ionothermal design of crystalline halogeno(cyano)cuprate family: structure diversity, solid-state luminescence, and photocatalytic performance, Inorganic Chemistry, 2017, 56, 7161-7174.
◙ Ying-Ying Xue, Li-Xia Zhang, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu, Quan-Guo Zhai*, Ionothermal synthesis of novel Pb–OH–Cu–X (X = Cl, Br and I) quaternary heterometallic frameworks with tunable optical properties, Dalton Transactions, 2017, 46, 5183-5188.
◙ Jian-Wei Zhang, Man-Cheng Hu,* Shu-Ni Li, Yu-Cheng Jiang, Quan-Guo Zhai*, Ligand torsion triggered two robust Fe-tetratopic carboxylate frameworks with enhanced gas uptake and separation performance, Chemistry - A European Journal, 2017, 23, 6693–6700.
◙ Xiao-Ying Bai, Wen-Juan Ji, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu, Quan-Guo Zhai*, Nonlinear optical rod indium-imidazoledicarboxylate framework as room-temperature gas sensor for butanol isomers, Crystal Growth & Design, 2017, 17, 423−427.
◙ Ying-Ying Xue, Jin-Lian Wang, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu*, Quan-Guo Zhai*, Mesoporous Ag/In2O3 composite derived from indium organic framework as high performance formaldehyde sensor, Journal of Solid State Chemistry, 2017, 247, 170–175.
◙ Jian-Wei Zhang, Man-Cheng Hu*, Shu-Ni Li, Yu-Cheng Jiang, Quan-Guo Zhai*, Microporous rod metal-organic frameworks with diverse Zn/Cd-triazolate ribbons as secondary building units for CO2 uptake and selective adsorption of hydrocarbons, Dalton Transactions, 2017, 46, 836–844.
◙ Kun Wang, Shuni Li, Yucheng Jiang, Mancheng Hu, Quan-Guo Zhai*, A pillar-layered metal-organic framework as luminescent sensor for selective and reversible response of chloroform, Journal of Solid State Chemistry, 2017, 247, 39–42.
◙ Yuan Wang, Xitong Chen, Qipu Lin, Aiguo Kong, Quan-Guo Zhai, Shilei Xie, Pingyun Feng, Nanoporous carbon derived from a functionalized metal–organic framework as a highly efficient oxygen reduction electrocatalyst, Nanoscale, 2017, 9, 862-868.
2016
◙ Quan-Guo Zhai, Xianhui Bu, Chengyu Mao, Xiang Zhao, Luke Daemen, Yongqiang Cheng, Anibal J. Ramirez-Cuesta, Pingyun Feng, An ultra-tunable platform for molecular engineering of high-performance crystalline porous materials, Nature Communications, 2016, 7: 13645 | DOI: 10.1038/ncomms13645.
◙ Quan-Guo Zhai, Xianhui Bu; Chengyu Mao, Xiang Zhao, Pingyun Feng, Systematic and dramatic tuning on gas sorption performance in heterometallic metal-organic frameworks, Journal of the American Chemical Society, 2016, 138, 2524-2527.
◙ Jian-Wei Zhang, Man-Cheng Hu*, Shu-Ni Li, Yu-Cheng Jiang, and Quan-Guo Zhai*, Design of highly connected Cd-tetrazolate-dicarboxylate frameworks with enhanced CO2/CH4 and C2 hydrocarbons/CH4 separation performance, Crystal Growth & Design, 2016, 16, 6430-6435.
◙ Xiang Zhao, Xianhui Bu, Edward T. Nguyen, Quan-Guo Zhai, Chengyu Mao, Pingyun Feng, Multivariable modular design of pore space partition, Journal of the American Chemical Society, 2016, 138, 15102-15105.
◙ Quan-Guo Zhai, Xianhui Bu, Xiang Zhao, Chengyu Mao, Fei Bu, Xitong Chen, Pingyun Feng, Advancing magnesium-organic porous materials through new magnesium cluster chemistry, Crystal Growth & Design, 2016, 16, 1261-1267.
◙ Xitong Chen, Xianhui Bu, Qipu Lin, Quan-Guo Zhai, Xiang Zhao, Yuan Wang, Pingyun Feng, Organization of lithium cubane clusters into three-dimensional porous frameworks by self-penetration and self-polymerization, Crystal Growth & Design, 2016, 16, 6531−6536.
◙ Xiang Zhao, Chengyu Mao, Karen Tu Luong, Qipu Lin, Quan-Guo Zhai, Pingyun Feng, Xianhui Bu, Framework cationization by preemptive coordination of open metal sites for anion-exchange encapsulation of nucleotides and coenzymes, Angewandte Chemie International Edition, 2016, 55, 2768-2772.
◙ Jin-Lian Wang, Quan-Guo Zhai*, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu, Mesoporous In2O3 materials prepared by solid-state thermolysis of indium-organic frameworks and their high HCHO-sensing performance, Inorganic Chemistry Communications, 2016, 63, 48-52.
◙ Li-Xia Zhang, Quan-Guo Zhai*, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu, [AgPb2I3(OH)2]: An unprecedented quaternary heterometallic semiconducting framework synthesized under ionothermal condition, Inorganic Chemistry Communications, 2016, 67, 6-9.
◙ Xiao Wang, Xiang-Yang Hou*, Quan-Guo Zhai*, Man-Cheng Hu, Two novel CPs with double helical chains based rigid tripodal ligands: Syntheses, crystal structures, magnetic susceptibility and fluorescence properties, Journal of Molecular Structure, 2016, 1123, 394-399.
2015
◙ Quan-Guo Zhai, Chengyu Mao, Xiang Zhao, Qipu Lin, Fei Bu, Xitong Chen, Xianhui Bu, Pingyun Feng, Cooperative crystallization of heterometallic indium–chromium metal–organic polyhedra and their fast proton conductivity, Angewandte Chemie International Edition, 2015, 54, 7886-7890.
◙ Xiang Zhao, Xianhui Bu, Quan-Guo Zhai, Huy Tran, Pingyun Feng, Pore space partition by symmetry-matching regulated ligand insertion and dramatic tuning on carbon dioxide uptake, Journal of the American Chemical Society, 2015, 137, 1396-1399.
◙ Quan-Guo Zhai, Ni Bai, Shuni Li, Xianhui Bu, Pingyun Feng, Design of pore size and functionality in pillar-layered Zn-triazolate-dicarboxylate frameworks and their high CO2/CH4 and C2 hydrocarbons/CH4 selectivity, Inorganic Chemistry, 2015, 54, 9862-9868.
◙ Fei Bu, Qipu Lin, Quan-Guo Zhai, Xianhui Bu, Pingyun Feng, Charge-tunable indium–organic frameworks built from cationic, anionic, and neutral building blocks, Dalton Transactions, 2015, 44,16671-16674.
◙ Shuang-Qiu Chen, Quan-Guo Zhai*, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu*, Channel partition into nanoscale polyhedral cages of a triple-self-interpenetrated metal–organic framework with high CO2 uptake, Inorganic Chemistry, 2015, 54, 10-12.
◙ Xing-Xia Wang, Quan-Guo Zhai*, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu, Porous Cd-carboxylate frameworks tuned by the bulk of linker: Interpenetrated nets, selective CO2 uptakes and high water vapor adsorption, Inorganic Chemistry Communications, 2015, 61, 200-203.
◙ Xiao-Li Yan, Shu-Ni Li*, Yu-Cheng Jiang, Man-Cheng Hu, Quan-Guo Zhai*, Synthesis, crystal structures and gas adsorption of two porous pillar-layered MOFs decorated with different functional groups, Inorganic Chemistry Communications, 2015, 62, 107-110.
◙ Ni Bai, Shu'ni Li*, Yucheng Jiang, Mancheng Hu, Quan-Guo Zhai*, Pillar-layered Zn–triazolate–carboxylate frameworks tuned by the bend angles of ditopic ligands, Inorganic Chemistry Communications, 2015, 53, 84-87.
2014
◙ A. C. L. Jones, H. J. Goldman, Quan-Guo Zhai, P. Feng, H. W. K. Tom, and A. P. Mills, Jr. Monoenergetic positronium emission from metal-organic framework crystals, Physical Review Letters, 2015, 114, 153201.
◙ Wen-Juan Ji, Man-Cheng Hu, Shu-Ni Li, Yu-Cheng Jiang, Quan-Guo Zhai*, Ionic liquids introduced into supramolecular isomeric open-frameworks as photocatalyst for visible-light-driven degradation of organic dyes, CrystEngComm, 2014, 16, 3474-3477.
◙ Xiao Wang, Quan-Guo Zhai*, Shuni Li, Yucheng Jiang, Mancheng Hu*, Synthesis, crystal structures and solid state luminescent properties of diverse Ln-pyridine-3,5-dicarboxylate coordination polymers modulated by the ancillary ligand, Crystal Growth & Design, 2014, 14, 177−188.
◙ Xiao Wang, Quan-Guo Zhai*, Xiang-Yang Hou, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu*, Ligand configuration introduced into a 3D self-interpenetrated coordination polymer as visible-light-driven photocatalyst, Inorganic Chemistry Communications, 2014, 45, 1-4.
2013
◙ Quan-Guo Zhai*, Rong-Rong Zeng, Shu-Ni Li, Yu-Cheng Jiang and Man-Cheng Hu*, Alkyl substituents introduced into novel d10-metalimidazole-4,5-dicarboxylate frameworks: synthesis, structure diversities and photoluminescence properties, CrystEngComm, 2013, 15, 965-976.
◙ Wen-Juan Ji, Quan-Guo Zhai*, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu*, An anionic metal–organic framework based on infinite [In3(μ3-OH)2]n inorganic chains synthesized in ionic liquid, Inorganic Chemistry Communications, 2013, 28, 16-19.
◙ Quan-Guo Zhai*, Yong-Ni Zhao, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu, Assembly of CuBr and 1,6-bi(benzotriazole)hexane under solvothermal conditions modulated by alkali metal cations, Inorganic Chemistry Communications, 2013, 35, 31-33.
◙ Yan-Ting Feng, Shu-Ni Li, Quan-Guo Zhai*, Yu-Cheng Jiang, Man-Cheng Hu, A luminescent Cu(I)-CN-1,2,4-triazolate open-framework with unique 2-fold interpenetrated (4, 6)-connected fsc topology, Inorganic Chemistry Communications, 2013, 36, 150-154.
◙ Yong-Ni Zhao, Cui-Cui Zhang, Quan-Guo Zhai*, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu, Solvent-introduced two novel copper(II)–letrozolate compounds: solvothermal synthesis, crystal structures and photoluminescence property, Inorganica Chimica Acta, 2013, 405, 176-181.
◙ Quan-Guo Zhai, Shuang-Qiu Chen, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu, A luminescent rod-packing organic–inorganic hybrid framework based on copper(I) cyanide ribbon and 5-(4-pyridine)tetrazole ligand, Journal of Inorganic and Organometallic Polymers and Materials, 2013, 23, 1195-1200.
◙ Yan-Hua, Zhang, Shu-Ni Li*, Man-Cheng Hu, Yu-Cheng Jiang, Quan-Guo Zhai*, Synthesis, crystal structure, and blue photoluminescence of a 3D coordination polymer based on a Ag10 cluster with the versatile 2-mercapto-5-benzimidazolesulfonic acid ligand, Journal of Coordination Chemistry, 2013, 66(13), 2316-2324.
◙ Quan-Guo Zhai*, Cheng-Feng Zhang, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu, Synthesis, structure, and photoluminescence of a (4,6)-connected Cu(I)–CN–triazolate framework built with a unique heptanuclear hybrid cluster, Journal of Coordination Chemistry, 2013, 66(22), 4004-4014.
2012
◙ Quan-Guo Zhai, Qipu Lin, Tao Wu, Le Wang, Shou-Tian Zheng, Xianhui Bu, Pingyun Feng, High CO2 and H2 uptake in an anionic porous framework with amino-decorated polyhedral cages, Chemistry of Materials, 2012, 24, 2624-2626.
◙ Quan-Guo Zhai, Qipu Lin, Tao Wu, Shou-Tian Zheng, Xianhui Bu, Pingyun Feng, Induction of trimeric [Mg3(OH)(CO2)6] in a porous framework by a desymmetrized tritopic ligand, Dalton Transactions, 2012, 41, 2866-2868.
◙ Fei Bu, Qipu Lin, Quan-Guo Zhai, Le Wang, Tao Wu, Shoutian Zheng, Xianhui Bu, Pingyun Feng, Two zeolite‐type frameworks in one metal–organic framework with Zn24@Zn104 cube‐in‐sodalite architecture, Angewandte Chemie International Edition, 2012, 51, 8538-8541.
◙ Rui Ding, Quan-Guo Zhai*, Jing-Ping Niu, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu*, Crystalline 3D open-framework halogeno(cyano)cuprates synthesized in ionic liquids, CrystEngComm, 2012, 14, 2626-2629.
◙ Quan-Guo Zhai*, Rui Ding, Shu-Ni Li, Yu-Cheng, Jiang, Man-Cheng Hu, A (3,9)-connected cadmium 1,2,4-triazolate framework based on a trinuclear inorganic cluster, Journal of Coordination Chemistry, 2012, 65, 516–524.
◙ Wen-Juan Ji, Quan-Guo Zhai*, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu*, The ionothermal synthesis of a 3D indium metal–organic framework: Crystal structure, photoluminescence property and photocatalytic activity, Inorganic Chemistry Communications, 2012, 24, 209–211.
2011
◙ Wen-Juan Ji, Quan-Guo Zhai*, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu*, The first ionothermal synthesis of a 3D ferroelectric metal–organic framework with colossal dielectric constant, Chemical Communications, 2011, 47, 3834–3836.
◙ Fei Hu, Quan-Guo Zhai*, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu*, Ionothermal synthesis of a new (4,12)-connected heterometallic iodoplumbate with [Pb4(OH)4] cubane as joint points of the helices, CrystEngComm, 2011, 13, 414-417.
◙ Quan-Guo Zhai*, Xia Gao, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu*, Solvothermal synthesis, crystal structures and photoluminescence properties of the novel Cd/X/a,ω-bis(benzotriazole)-alkane hybrid family (X = Cl, Br and I), CrystEngComm, 2011, 13, 1602-1611.
◙ Quan-Guo Zhai*, Jing-Ping Niu, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu*, Stuart R. Batten, An unusual uninodal 10-connected self-penetrating network built from sixteen-nuclear hybrid cadmium clusters, CrystEngComm, 2011, 13, 4508–4511.
◙ Rong-Rong Zeng, Quan-Guo Zhai*, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu*, An unusual (3,6)-connected microporous metal–organic framework based on tetrahedral Zn4 clusters with selective adsorption of CO2, CrystEngComm, 2011, 13, 4823–4826.
◙ Jing-Ping Niu, Quan-Guo Zhai*, Jun-Hua Luo, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu, Ionothermal synthesis, structure and optical properties of three new organic–inorganic hybrid imidazolium bromoplumbate complexes, Inorganic Chemistry Communications, 2011, 14, 663-666.
◙ Quan-Guo Zhai*, Cui-Cui Zhang, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu*, Synthesis, structure and characterizations of a novel 3D coordination polymer constructed from rare castellated inorganic chains, Inorganic Chemistry Communications, 2011, 14, 1982-1985.
◙ Shu-Ni Li*, Quan-Guo Zhai, Man-Cheng Hu, Yu-Cheng Jiang, Synthesis and crystal structures of two novel complexes with N-[2-(5-bromo-2-hydroxybenzylideneamino)ethyl]-4-methylbenzene-sulfonamide as ligand, Journal of Chemical Crystallography, 2011, 41, 12-16.
2010
◙ Xia Gao, Quan-Guo Zhai, Shu-Ni Li, Rui Xia, Hai-Juan Xiang, Yu-Cheng Jiang, Man-Cheng Hu*, Two anionic [CuI6X7]nn- (X = Br and I) chain-based organic-inorganic hybrid solids with N-substituted benzotriazole ligands, Journal of Solid State Chemistry, 2010, 183, 1150-1158.
◙ Quan-Guo Zhai*, Rui Ding, Shu-Ni Li, Wen-Juan Ji, Xia Gao, Yu-Cheng Jiang, Man-Cheng Hu*, Ligand-configuration-dependent hybrid supramolecular isomers based on the octamolybdate building blocks from one-pot hydrothermal crystallization, Inorganica Chimica Acta, 2010, 363, 653-661.
◙ Quan-Guo Zhai*, Shu-Ni Li, Xia Gao, Wen-Juan Ji, Yu-Cheng Jiang, Man-Cheng Hu*, Self-assembly of a novel 3D copper(I)–tetrazolate supramolecular framework via interpenetration of porous 2D double-layer motifs, Inorganic Chemistry Communications, 2010, 13, 211-214.
◙ Quan-Guo Zhai*, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu*, A Cd/triazolate/carboxylate metal–organic framework with unprecedented (3,10)-connected topology based on tetranuclear clusters, Inorganic Chemistry Communications, 2010, 13, 891-894.
◙ Quan-Guo Zhai, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu*, A mixed-valence chair-like tetranuclear copper(I,II) cluster with three linking modes of the 3,5-bis(2-pyridyl)-1,2,4-triazole ligand, Acta Crystallographica Section C, 2010, C66, m249-m252.
◙ Gao Xia, Quan-Guo Zhai*, Xue-jing Dui, Shu-Ni Li, Yu-Cheng Jiang, Man-Cheng Hu*, Synthesis, crystal structure, and characterizations of a 3-D Cu(I) complex with 1,6-bi(benzotriazole)hexane, Journal of Coordination Chemistry, 2010, 63, 214-222.
◙ Shu-Ni Li*, Quan-Guo Zhai, Man-Cheng Hu*, Yu-Cheng Jiang, Two coordination polymers constructed from pillared M-O (M = Na+ or Ba2+) subunits with 3-formyl-4-hydroxybenzene-sulfonic acid as ligand, Zeitschrift fur Anorganische und Allgemeine Chemie, 2010, 636, 1142-1146.
2009及以前
◙ Man-Cheng Hu*, Yan Wang, Quan-Guo Zhai*, Shu-Ni Li, Yu-Cheng Jiang, Yong Zhang, Synthesis, crystal structures, and photoluminescent properties of the Cu(I)/X/α,ω-bis(benzotriazole)alkane hybrid family (X = Cl, Br, I, and CN), Inorganic Chemistry, 2009, 48, 1449-1468.
◙ Shu-Ni Li*, Quan-Guo Zhai, Man-Cheng Hu, Yu-Cheng Jiang, Synthesis, crystal structures and characterization of two Cu(II) complexes with asymmetric sulfonamide Schiff-base ligands, Journal of Coordination Chemistry, 2009, 62, 2709-2718.
◙ Shu-Ni Li, Quan-Guo Zhai, Man-Cheng Hu*, Yu-Cheng Jiang, Synthesis, crystal structures and characterization of three novel complexes with N-[2-(2-hydroxybenzylideneamino)ethyl]-4-methyl-benzene-sulfonamide as ligand, Inorganica Chimica Acta, 2009, 362, 2217-2221.
◙ Yan Wang, Man-Cheng Hu*, Quan-Guo Zhai*, Shu-Ni Li, Yu-Cheng Jiang, Wen-Juan Ji, Synthesis, structure and luminescent properties of an organic–inorganic hybrid solid based on unprecedented flower-basket-shaped [CuI4I4] clusters with 1,2-bis(benzotriazole)ethane ligands, Inorganic Chemistry Communications, 2009, 12, 281-285.
◙ Quan-Guo Zhai*, Man-Cheng Hu, Yan Wang, Wen-Juan Ji, Shu-Ni Li, Yu-Cheng Jiang, Synthesis and characterizations of a novel dia-type Ag–BPT coordination polymer with tetranuclear motifs as jointing points (BPT = 3,5-bis(3-pyridyl)-1,2,4-triazole), Inorganic Chemistry Communications, 2009, 12, 286-289.
◙ Quan-Guo Zhai*, Jing-Ping Niu, Man-Cheng Hu, Yan Wang, Wen-Juan, Ji, Shu-Ni Li, Yu-Cheng Jiang, Hydrothermal synthesis, crystal structures, and blue photoluminescence of two 2-D Ag-1,2,4-triazolate coordination polymers with 4462 topology, Journal of Coordination Chemistry, 2009, 62, 2927-2936.
◙ Quan-Guo Zhai, Shu-Ni Li, Man-Cheng Hu*, Yu-Cheng Jiang, A three-dimensional hybrid framework based on novel [Co4Mo4] bimetallic oxide clusters with 3,5-bis(3-pyridyl)-1,2,4-triazole ligands, Acta Crystallographica Section C, 2009, C65, m128-m130.
◙ Quan-Guo Zhai, Man-Cheng Hu*, Shu-Ni Li, Yu-Cheng Jiang, Synthesis, structure and blue luminescent properties of a new silver(I) triazolate coordination polymer with 8210-a topology, Inorganica Chimica Acta, 2009, 362, 1355-1357.
◙ Can-Zhong Lu, Quan-Guo Zhai, Xiao-Yuan Wu, Li-Juan Chen, Shu-Mei Chen, Zhen-Guo Zhao, Xiao-Yu Jiang, Construction of some organic-inorganic hybrid complexes based on polyoxometalates, DESIGN AND CONSTRUCTION OF COORDINATION POLYMERS, Mao-Chun Hong & Ling Chen, John Wiley & Sons Inc. Publication, pp 87-110, 2009.
◙ Quan-Guo Zhai, Man-Cheng Hu*, Shu-Ni Li, Yu-Cheng Jiang, A three-dimensional organic–inorganic hybrid solid constructed from novel Mo-O-Zn bimetallic oxide networks linked via 3-amino-1,2,4-triazole, Inorganic Chemistry Communications, 2008, 11, 1147-1150.
◙ Wen-Juan Ji, Quan-Guo Zhai*, Man-Cheng Hu*, Shu-Ni Li, Yu-Cheng Jiang, Yan Wang, Ionothermal synthesis and characterization of a 3-D (4,8)-connected porous anionic metal–organic framework entrapped with 1-D [K2(H2O)6] chains, Inorganic Chemistry Communications, 2008, 11, 1455–1458.
◙ Quan-Guo Zhai, Xiao-Yuan Wu, Shu-Mei Chen, Zhen-Guo, Zhao, Can-Zhong Lu, Construction of Ag/1,2,4-triazole/polyoxometalates hybrid family varying from diverse supramolecular assemblies to 3-D rod-packing framework, Inorganic Chemistry, 2007, 46 (12), 5046-5058.
◙ Quan-Guo Zhai, Can-Zhong Lu, Xiao-Yuan Wu, Stuart R. Batten, Coligand modulated six-, eight-, and ten-connected Zn/Cd-1,2,4-triazolate frameworks based on mono-, bi-, tri-, penta-, and heptanuclear cluster units, Crystal Growth & Design, 2007, 7(11), 2332-2342.
◙ Quan-Guo Zhai, Xiao-Yuan Wu, Shu-Mei Chen, Li-Juan Chen, Can-Zhong Lu, Keggin polyoxometalates-supported assembly of 2D supramolecular isomers: synthesis, crystal structures and characteristics of two novel hybrid host-guest complexes, Inorganica Chimica Acta, 2007, 360, 3484-3492.
◙ Quan-Guo Zhai, Xiao-Yuan Wu, Shu-Mei Chen, Can-Zhong Lu, Wen-Bin Yang, Construction of Cd/Zn(II)-1,2,4-triazolate coordination complexes via changing substituents and anions, Crystal Growth & Design, 2006, 6(9), 2126-2135.
◙ Quan-Guo Zhai, Can-Zhong Lu, Shu-Mei Chen, Xin-Jiang Xu, Wen-Bin Yang, Design of novel three-dimensional coordination polymers based on triangular trinuclear copper 1,2,4-triazolate units, Crystal Growth & Design, 2006, 6(6), 1393-1398
◙ uan-Guo Zhai, Can-Zhong Lu , Quan-Zheng Zhang, Xiao-Yuan Wu, Xin-Jang Xu, Shu-Mei Chen, Li-Juan Chen, Influence of substituents on the structures of hybrid complexes constructed from tetranuclear copper(I) 1,2,4-triazolate clusters and octamolybdates, Inorganica Chimica Acta, 2006, 359, 3875-3887.
◙ Quan-Guo Zhai, Can-Zhong Lu, Shu-Mei Chen, Xin-Jiang Xu, and Wen-Bin Yang, A novel 3D hybrid architecture based on (H2O)6 encircling Cu4I4-O-Cu4I4 cluster and hexanuclear Cu6(datrz)6 ring, Inorganic Chemistry Communications, 2006, 9, 819-822.
◙ Chun-Yu Geng, Man-Cheng Hu, Shu-Ni Li, Quan-Guo Zhai, Yu-Cheng Jiang, Zhi-Hong Liu, Preparation, Crystal Structure and Thermodynamic Properties of Cs(ATZ), Chinese Journal of Organic Chemistry, 2005, 63 (21): 1974-1978.
◙ Shu-Mei Chen, Can-Zhong Lu, Chang-Kun Xia, Xin-Jiang Xu, Quan-Guo Zhai, Reactivity of 1,4-Bis[2-(5-phenyloxazoly)]benzene toward Cu Salts under Different Reaction Conditions, Crystal Growth & Design, 2005, 5(4), 1485- 1490.
◙ Ya-Qin Yu, Can-Zhong Lu, Xin-Jiang Xu, Jiu-Hui Liu, Quan-Guo Zhai,Three-dimensional porous framework formed by [Fe4Mo6O26]4− anions belts in brick-wall mode, Inorganic Chemistry Communications, 2005, 8, 635-637.
二、专利情况
◙ 翟全国,薛颖颖,李淑妮,胡满成,蒋育澄, 铜-吡嗪配体调控孔尺寸的金属有机框架材料及其制备方法和纯化甲烷的应用,中国发明专利,ZL202010953053.0。
◙ 翟全国,李永鹏,胡满成,李淑妮,蒋育澄, 一种稳定的多孔钴配合物及其制备方法和在吸附、分离小分子中的应用,中国发明专利,ZL201811454684.7。
◙ 翟全国,雷娇,胡满成,李淑妮,蒋育澄, 2,5-二羟基对苯二甲酸铟配合物及其制备方法和荧光检测水合联胺的应用,中国发明专利,ZL201811454642.3。
◙ 翟全国,李永鹏,赵永妮,胡满成,李淑妮,蒋育澄, 一种多孔镍配合物及其制备方法和在吸附乙烯和水果保鲜中的应用,中国发明专利,ZL201810999546.0。
◙ 翟全国,李永鹏,胡满成,李淑妮,蒋育澄, 一种多孔金属有机配合物及其制备方法和在检测氨气、氨水中的应用, 中国发明专利,ZL201810543523.9。
◙ 翟全国,李永鹏,胡满成,李淑妮,蒋育澄, 一种多孔钴配合物及其制备方法和在吸附、分离气体小分子中的应用,中国发明专利,ZL201810999561.5。
◙ 翟全国,王坤,李淑妮,胡满成,蒋育澄,一类双金属多孔配合物及其制备方法,中国发明专利,ZL201710043435.8。
◙ 翟全国,王坤,李淑妮,胡满成,蒋育澄,一类柱层多孔配合物及其制备方法,中国发明专利,ZL201710043544.X。
◙ 翟全国,白晓颖,李淑妮,胡满成,蒋育澄,一类四氮唑多孔配合物的制备方法,中国发明专利,ZL201710043486.0。
◙ 翟全国,冯燕婷,李淑妮,胡满成,蒋育澄,1,4-对苯二甲酸调控的多氮唑配位聚合物及其制备方法,中国发明专利,ZL201410138152.8。
◙ 翟全国,赵永妮,李淑妮,胡满成,蒋育澄,具备小分子气体高存储能力的过渡金属多孔配合物材料及其制备方法,中国发明专利,ZL201410014549.6。
◙ 翟全国,籍文娟,胡满成,李淑妮,蒋育澄,杂多钨酸阴离子和烷基咪唑阳离子的复合物及制备方法,中国发明专利,ZL201310244604.6。
◙ 翟全国,张翠翠,李淑妮,胡满成,蒋育澄,呋喃-2,5-二羧酸金属配位聚合物及其制备方法,中国发明专利,ZL201310153103.7。
三、获奖情况
◙ 陕西美高梅注册"教书育人奖"(2020年);
◙ 陕西美高梅注册美高梅注册优秀党支部书记(2020年);
◙ 陕西美高梅注册美高梅注册“最喜爱的老师”(2020年);
◙ 新型光电功能配合物的结构设计与性能调控,陕西高等学校科学技术奖,一等,1/9(2020年);
◙ 陕西美高梅注册美高梅注册首届“卓越教师成长基金”优秀教师(2020年);
◙ 稀碱金属铷、铯盐分离纯化的基础溶液化学研究, 陕西省自然科学奖,二等,3/4(2019年);
◙ 教育部“高层次人才奖励计划”青年学者(2018年);
◙ 教育部首批100个全国高校“双带头人”教师党支部书记工作室(2018年);
◙ 陕西美高梅注册优秀党支部书记(2018年);
◙ 陕西美高梅注册美高梅注册“腾飞计划学者”(2017年);
◙ 陕西美高梅注册研究生优质课教师评选二等奖(2017年);
◙ 重稀碱金属铷、铯分离纯化的基础溶液化学研究,陕西高等学校科学技术奖,一等,3/8(2017年);
◙ 陕西省“青年科技新星”(2014年);
◙ 教育部“新世纪优秀人才”(2012年);
◙ 陕西美高梅注册首届青年教师教学基本功大赛优秀奖(2008年);
◙ 重稀碱金属(铷、铯)的相化学、纯化工艺及其在生物模拟体系中的溶液化学研究,陕西省科学技术奖,三等(2007年)。
四、教学情况
[1] 承担课程
◙ 本科生:无机化学(上、下)、无机化学实验、化学学科专业引导、化学前沿讲座等
◙ 研究生:配位化学与晶体工程、化学的力量等
[2] 教学论文
◙ 翟全国,黄静伟,包永胜,伍晓春,陈卓,郭珍,房喻*,“西部高校化学(师范)专业建设虚拟教研室”- 基本情况和建设思考, 大学化学,2023.
◙ 翟全国*,薛东,魏灵灵,胡满成,高胜利*,突出“专业-能力-素质融合”是升华无机化学课程设计的核心—重构“基础无机化学”教学设计,大学化学,2022。
◙ 翟全国*,李淑妮,魏灵灵,蒋育澄,高玲香,胡满成,高胜利*,基础无机化学“物质状态”课程设计怎样解决“衔接-基础-提升”矛盾,大学化学,2022。
◙ 翟全国,蒋育澄,胡满成,李淑妮,高胜利,从原子量概念的准确性和测定技术的发展看科学进步,化学教育,2022,144-150。
◙ 翟全国,蒋育澄,胡满成,李淑妮*,高胜利,“元素与元素周期律”课程设计如何体现“知识-能力-素质有机融合”,大学化学,2022,37(X),2202048。
◙ 薛东,高玲香,胡满成,翟全国*,张伟强,刘志宏,高胜利,突出创新思维和科学研究是加强无机化学教材建设的前提—编写《美高梅注册》,大学化学,2022,37(X),2111044。
◙ 王晓明,马艺,徐媛,陈亚芍,翟全国,胡满成,薛亮,魏灵灵,焦桓,面向未来卓越中学化学教师培养的一流化学专业建设,大学化学,2022,37(X),2108079。
◙ 魏灵灵,李淑妮,马艺,翟全国,高胜利,高玲香,非金属元素氮的同素异形体概述,化学教育,2021,42(4), 17-30。
◙ 马艺,张伟强,薛东旭,张航,顾泉,郑浩铨,翟全国,高玲香,多维度构建和实施线上实验课堂的探索与实践,大学化学,2020,35(5),229-235。
◙ 高玲香,张姝颖,张伟强,翟全国,胡满成,高胜利,摩尔新定义和准确测定的阿伏伽德罗常数,大学化学,2020,35 (8),67-74。
◙ 李淑妮,翟全国,蒋育澄,胡满成,杨 奇,高胜利,原子间的另一种作用力---氢键,化学教育,2019,40(22),15-20。
◙ 李淑妮,翟全国,蒋育澄,胡满成,刘志宏,高胜利,元素周期表与化学教育---纪念门捷列夫元素周期表发表 150 周年,大学化学,2019,34 (12),2−7。
◙ 李淑妮,翟全国,蒋育澄,胡满成,如何在基础无机化学实验课中培养本科生的科研思维--以实验“[Co(NH3)6]Cl3的制备”的改革为例,大学化学,2018,33(3),36-41。
◙ 翟全国,李淑妮,蒋育澄,胡满成,配位聚合物[Cu2I(DETRZ)]n合成与表征的综合型实验教学设计,实验室研究与探索,2014, 33(2), 155-160。
◙ 翟全国,李淑妮,蒋育澄,胡满成,高师院校无机化学实验教学效果提升的实践与体会,广州化工,2013, 41(9), 216-217, 242。
◙ 蒋育澄,李淑妮,翟全国,元素的生物效应在元素化学教学中的渗透与融合,大学化学,2009,24(4), 35-39 & 70。
[3] 出版教材
◙ 《美高梅注册》,科学出版社,共计22分册,副主编,2019年-2023年。
◙ 《美高梅注册》,北京美高梅注册出版社,参编,2016年。
◙ 《美高梅注册》,高等教育出版社,参编,2016年。
◙ 《美高梅注册》,北京美高梅注册出版社,参编,2014年。
[4] 教学项目
◙ 陕西美高梅注册首届“课程思政育人优秀教学团队”(无机化学),课程团队负责人,2022年。
◙ 陕西美高梅注册首届“课程思政示范课程”(无机化学),课程负责人,2022年。
◙ 刘志宏,高玲香,魏灵灵,李淑妮,翟全国,陕西省一流本科课程,无机化学,2021年。
◙ 高玲香,翟全国,张伟强,马艺,顾泉等,国家一流本科课程,人工光合成清洁燃料综合化学虚拟仿真实验,2020年。
◙ 翟全国,陕西美高梅注册“课程思政”示范课建设项目---无机化学,1万元,主持,2019年。
◙ 翟全国,陕西美高梅注册研究生教育教学改革项目(研究生优质课程项目),“配位化学与晶体工程”,GERP-18-07, 2018.1-2020.12, 3万元,主持。
[5] 指导本科生实践情况
◙ 王正元,张琪琪,张宇璠,簇-簇型MOFs的设计合成及气体吸附性能,2023年大学生创新创业训练计划项目,省级。
◙ 肖懿,潘冬辰,樊冠江,何家乐,新型MOF乙烯吸附剂的设计合成及其果蔬保鲜性能研究,2022年大学生创新创业训练计划项目,国家级。
◙ 肖懿,樊冠江,潘冬辰,席幕辰,李翊嘉,“鲜”果“常”存—MOF果蔬保鲜剂,2022年“挑战杯”大学生创业计划竞赛,校级铜奖。
◙ 员柔,刘欣,李珊,闫芙堃,自校准MOF荧光温度计研究,2021年大学生创新创业训练计划项目,省级。
◙ 原潇,齐倩倩,范烨,王荣欣,方阳,双层MOF催化剂的可控制备及其电解水性能研究,2020年大学生创新创业训练计划项目,国家级。
◙ 祝晓晗,邵理阳,张荣荣,吴洋,基于ESIPT机理构建MOF荧光传感器研究,2019年大学生创新创业训练计划项目,国家级。
课题组情况简介
一、仪器设备情况
二、指导研究生情况
◙ 2006级: 籍文娟 (合作指导) 王艳 (合作指导)
◙ 2007级: 高霞 (合作指导)
◙ 2008级: 牛净平 胡菲 (合作指导)
◙ 2009级: 丁瑞 曾蓉蓉(合作指导) 籍文娟 (博士生 合作指导)
◙ 2010级: 张翠翠 张艳华(合作指导)
◙ 2011级: 赵永妮 冯燕婷 (合作指导) 王潇 (博士生 合作指导)
◙ 2012级: 陈双秋 张成凤 白妮 (合作指导)
◙ 2013级: 王金连 王兴霞 张丽霞 闫小丽
◙ 2014级: 王坤 白晓颖 张建伟 (博士生 合作指导)
◙ 2015级: 张雅丽 薛颖颖
◙ 2016级: 李永鹏 (博士生) 李海鹏 雷小娟 杜振强 (合作指导) 豆昭迪 (合作指导)
◙ 2017级: 雷娇 吕虹娟 韩国栋(合作指导)
◙ 2018级: 王颖 (师资博士后) 薛颖颖 (博士生)李运彤 路丽诗 霍嘉敏(合作指导)QADEER UL HASSAN (博士后)
◙ 2019级: 李海鹏(博士生,合作指导) 闫欣 范书聪 张晶 穆晓兵(合作指导)
◙ 2020级: 雷娇(博士生)吕虹娟(博士生 合作指导)于嘉(硕士生)王硕(硕士生)王佳雯(硕士生)
◙ 2021级: 范书聪(博士生)贺琬蓉(硕士生)李树一(硕士生)孟婕(硕士生)高存(硕士生)
◙ 2022级:王佳雯(博士生)杨立秋(硕士生)刘严营(硕士生)李丹(硕士生)李柔妤(硕士生)邵理阳(硕士生,合作指导)宋楠(硕士生,合作指导)吕俊霆(硕士生,合作指导)
欢迎积极上进、踏实认真的同学报考本课题组的硕士或博士研究生!
本课题组同时诚邀教授、副教授、博士后加盟!
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